Product ID:50-717 BLACK TREE (D-170)
MSDS Date:06/28/1991
FSC:8010
NIIN:01-273-9347
MSDS Number: BNWXH

NILES CHEMICAL PAINT CO

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MICHAEL LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

MINERAL SPIRITS (VAPOR PRESSURE 2.0 MM HG @ 20 C)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 49%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

AEROSOL PROPELLANT (VAPOR PRESSURE 70 PSIG)

CAS: 68476-86-8

Fraction By Weight: 22%

ACGIH TLV: 900 PPM

ALKYD RESIN

Fraction By Weight: 14%

COBALT COMPOUNDS (AS CO) (SARA 313)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE COMPOUNDS (AS MN) (SARA 313)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

PROPRIETARY INGREDIENTS (MANUFACTURER STATES UNIDENTIFIED

Fraction By Weight: BALANCE

4.73 LBS/GAL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRIT, LACRIMATION,
REDNESS, BLURRED VISION, VISUAL DISTURBANCES, EYE BURNS. SKIN:
HARMFUL IF ABSORBED THRU SKIN. BREATH: NASAL, RESP IRRIT, CNS
DEPRESS, ASPHYXIATION. SWALLOW: GASTROINTE ST IRRIT, BLINDNESS &
DEATH. UNCONSCIOUSNESS, COMA. TARGET ORGANS: LUNGS, SKIN, EYES,
RESP SYS, CNS, GI TRACT.
Explanation of Carcinogenicity:NONE.
Effects of Overexposure:BREATHING: CNS: DIZZINESS, DROWSINESS,
WEAKNESS, FATIGUE, CONFUSION, NAUSEA, HEADACHE, VERTIGO, POSSIBLE
UNCONSCIOUSNESS. SWALLOWING: ABDOMINAL PAIN, NAUSEA, VOMITING,
DIARRHEA.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHAL: MOVE TO FRESH AIR. IF BREATHING STOPPED, GIVE ARTIF
RESPIRATION. GET MED AID. SKIN: WASH W/SOAP & WATER. EYE: IMMED
FLUSH EYES W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN, LIFTING
EYELIDS OCCA S. GET IMMED MED AID. SWALLOWING: INDUCE VOMITING
IMMED BY GIVING 2 GLASSES WATER, STICK FINGER DOWN THROAT. NEVER
GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MED ATTENTION
IMMEDIATELY.

Flash Point Method:TCC
Flash Point:-99F,-73C
Lower Limits:0.8
Upper Limits:36.0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN POS
PRESS MODE & FULL PROTECT CLOTH. USE WATER TO COOL CLSD CNTNRS TO
PREVENT PRESS BLDUP/AUTO IGNIT/EXPLOS W/HEAT.
Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD. KEEP FROM HEAT/IGNIT
SOURECES. CLSD CNTNR MAY EXPLODE W/HEAT. APPLIC TO HOT SRFCS
REQUIRES SPECIAL PRECAUTIONS. DECOMP PROD MAY CAUSE HLTH HZD.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. MINIMIZE BREATHING
OF VAPORS AND AVOID SKIN CONTACT. ABSORB W/INERT MATERIAL (CLAY,
SOIL, COMMERCIALLY AVAILABLE ABSORBENT). SHOVEL RECLAIMED LIQUID
AND ABSORBENT INTO RECO VERY OR SALVAGE DRUMS FOR DISPOSAL.

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS.

Respiratory Protection:WEAR (TYPE TC-23C-75) FITTED HALF-MASK OR FULL
FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER APPLICATION UNLESS
AIR MONITORING DEMONSTRATES VAPOR/MIST LEVELS AREA BELOW APPLICABLE
LIMITS. FOLLOW RE SPIRATOR MFR'S DIRECTIONS FOR USE.
Ventilation:SUFF VENT (VOL/PATTRN)--KEEP AIR CONC BELOW PEL/TLV. REMOVE
DECOMP PROD (WELDING/FLAME CUT). VENT VAPOR EMIT ON HEATING.
Protective Gloves:NITRILE, VITON GLOVES.
Eye Protection:CHEM GOGGLES/SAFETY GLASSES/FACE SHIELD.
Other Protective Equipment:WEAR CHEM RESISTANT (NITRILE/VITON) CLOTHING
AS NEEDED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH CONTAM SKIN (IMMED). REMOVE CLOTH THAT
BECOMES WET (FLAMM). WASH BEFORE REUSE. WASH BEFORE EAT/SMOKE/USING
TOILET.
Supplemental Safety and Health
DO NOT WEAR CONTACT LENSES WHILE WORKING WITH THIS PRODUCT.

HCC:V3
Boiling Pt:B.P. Text:-10 TO 330F
Vapor Density:> AIR
Spec Gravity:6.59 LBS/GAL
Viscosity:55+-5S.#1Z
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:SLIGHT.
Appearance and Odor:LIQUID, ODODR OF SOLVENTS.
Percent Volatiles by Volume:83.80

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGATES AND DICHROMATES, STRONG
OXIDIZERS.
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.
Conditions to Avoid Polymerization:HGIH TEMPERATURES, SHOCK FROM
DROPPING.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.